Light emitting device

ABSTRACT

A light emitting device includes first and second light emitting elements, first and second color conversion material layers, a support member and a light reflective member. The first color conversion material layer has a first color conversion surface facing a first light extraction surface of the first light emitting element. The second color conversion material layer has a second color conversion surface facing a second light extraction surface of the second light emitting element. The support member supports the first and second color conversion material layers. The light reflective member covers a first side surface of the first light emitting element and a second side surface of the second light emitting element. At least a part of an upper surface of the light reflective member is positioned closer to the support member than the first color conversion material layer and the second color conversion material layer.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a continuation application of U.S. patentapplication Ser. No. 15/784,639, filed on Oct. 16, 2017, which is adivisional application of U.S. patent application Ser. No. 14/867,222,filed on Sep. 28, 2015, now U.S. Pat. No. 9,825,001. This applicationclaims priority to Japanese Patent Application No. 2014-201416 filed onSep. 30, 2014. The entire disclosures of U.S. patent application Ser.Nos. 15/784,639 and 14/867,222 and Japanese Patent Application No.2014-201416 are hereby incorporated herein by reference.

BACKGROUND 1. Field of the Invention

The present invention relates to a light emitting device and a methodfor manufacturing thereof.

2. Description of Related Art

As the quality of light emitting diodes has improved in recent years,they are used with various configurations in the field of generallighting, the field of automotive lighting, and so forth.

For example, an effort to obtain smaller and thinner light emittingdevices has been made.

Also, chromaticity and color reproducibility of a light emitting deviceimproved by using various kinds of color conversion materials incombination with a light emitting diode that has achieved high output,high brightness, and so forth (For example, JP 2012-119407A,JP2012-527742A, JP2013-197270A and WO2008/044759).

However, in recent years, color conversion materials with poordurability are becoming more frequently used, and in this case,obtaining a small and thin light emitting device with good chromaticityand color reproducibility may be difficult.

SUMMARY

It is an object of the present invention to provide a light emittingdevice and method for manufacturing thereof, with which a light emittingelement with a small and thin size can be obtained while desiredchromaticity and good color reproducibility can be achieved by a simplemethod.

A light emitting device according to the present disclosure includes afirst light emitting element, a second light emitting element, a firstcolor conversion material layer, a second color conversion materiallayer, a support member and a light reflective member. The first lightemitting element has a first electrode formation surface on which a pairof electrodes are arranged, a first light extraction surface oppositefrom the first electrode formation surface, and a first side surfaceextending between the first electrode formation surface and the firstlight extraction surface. The second light emitting element has a secondelectrode formation surface on which a pair of electrodes are arranged,a second light extraction surface opposite from the second electrodeformation surface, and a second side surface extending between thesecond electrode formation surface and the second light extractionsurface. The first color conversion material layer has a first colorconversion surface facing the first light extraction surface of thefirst light emitting element. The second color conversion material layerhas a second color conversion surface facing the second light extractionsurface of the second light emitting element. The support membersupports the first color conversion material layer and the second colorconversion material layer. The light reflective member covers the firstside surface of the first light emitting element and the second sidesurface of the second light emitting element. At least a part of anupper surface of the light reflective member is positioned closer to thesupport member than the first color conversion material layer and thesecond color conversion material layer.

According to the present disclosure, it is possible to provide a lightemitting device and method for manufacturing thereof, with which a lightemitting device with small and thin size can be obtained while evenbetter chromaticity and color reproducibility can be achieved by asimple method.

BRIEF DESCRIPTION OF DRAWINGS

FIGS. 1A to 1D are schematic manufacturing step diagrams showing amethod for manufacturing the light-transmissive member according to anembodiment of the present invention;

FIG. 2A is a schematic plan view of a light-transmissive memberaccording to an embodiment of the present invention;

FIG. 2B is a schematic plan view of a light-transmissive memberaccording to another embodiment of the present invention;

FIG. 2C is a schematic cross sectional view along the X-X′ line of thelight-transmissive member in FIG. 2B.

FIGS. 3A to 3D are schematic manufacturing step diagrams showing amethod for manufacturing the light-transmissive member according toanother embodiment of the present invention;

FIG. 4 is schematic plan view showing a light-transmissive memberaccording to still another embodiment of the present invention;

FIGS. 5A to 5C are schematic manufacturing step diagrams showing themethod for manufacturing a light emitting device according to anembodiment of the present invention;

FIGS. 6A to 6E are schematic manufacturing step diagrams showing amethod for manufacturing the light emitting device according to anembodiment of the present invention;

FIGS. 7A to 7F are schematic manufacturing step diagrams showing amethod for manufacturing the light emitting device according to anembodiment of the present invention;

FIG. 8 is schematic plan view of a light-transmissive member accordingto other embodiment of the present invention;

FIG. 9 is schematic plan view of a light-transmissive member accordingto still other embodiment of the of the present invention;

FIGS. 10A and 10B are schematic manufacturing step diagrams showing amethod for manufacturing the light emitting device according to otherembodiment of the present invention;

FIGS. 11A to 11C are schematic manufacturing step diagrams showing amethod for manufacturing a light emitting device according to stillother embodiment of the present invention;

FIGS. 12A to 12C are schematic plan view of a light emitting deviceaccording to other embodiment of the present invention;

FIGS. 13A to 13D are schematic plan view of a light emitting element ora light emitting device according to other embodiment of the of thepresent invention;

FIGS. 14A to 14C are schematic manufacturing step diagrams showing amethod for manufacturing the light emitting device according to stillother embodiment of the present invention;

FIGS. 15A and 15B are schematic manufacturing step diagrams showing amethod for manufacturing the light emitting device according to stillother embodiment of the present invention; and

FIG. 15C is a schematic lateral side view of FIG. 15B.

DETAILED DESCRIPTION

Embodiments for implementing the light emitting device and the methodfor manufacturing thereof of the present invention will be describedbelow with reference to the accompanying drawings. In the followingembodiment, the light emitting device and the method for manufacturingthereof that embody the technological concept of the present inventionare just examples, and unless otherwise specified, the constituent partsdiscussed in the embodiments are not intended to limit the scope of thepresent invention. Further, constitutions described in examples and theembodiments can be employed in other examples and embodiments.

The sizes and the arrangement relationships of the members in each ofdrawings are occasionally shown exaggerated for ease of explanation.

Light-Transmissive Member

The light-transmissive member of the present embodiment includes a sheetand a color conversion material layer. In one embodiment, thelight-transmissive member includes a light-reflective sheet that has athrough-hole, and a color conversion material layer that includes alight-transmissive resin containing a color conversion material anddisposed in the through-hole. The light-transmissive member preferablyhas suitable strength, and is self-standing. Therefore, it does notnecessarily have to be rigid, and it is preferably flexible enough sothat the color conversion material layer can be held without beingdamaged.

At least one of the same surface sides of the sheet and the colorconversion material layer, such as the upper surfaces, can be flush,that is, can be level or in a same plane, without any step between theirupper surfaces, as shown in FIG. 2C. The terms “flush”, “level”, “in thesame plane” and “without any step” here is intended to allow unevennessof about several dozen microns, and preferably about a few dozenmicrons. For example, these terms include the structure where nointentional processing is performed on the surfaces so that one of thesurfaces protrudes above the other. Accordingly, the dimensions of thecolor conversion material layer can be stabilized, and in turn those ofthe light-transmissive member, and thus proper assembly to the othermembers can be achieved. Stabilizing the dimensions of the lighttransmissive layer also allows facilitating to provide a lens or thelike on the upper surface of the color conversion material layer.

Alternatively, the color conversion material layer may have recessand/or protrusion (concave and/or convex) with respect to the uppersurface and/or the lower surface of the sheet (see thelight-transmissive members 10A to 10H in FIG. 8). In the case where thecolor conversion material layer is concave, light convergence or anothersuch effect can be exhibited. In the case where it is convex withrespect to the lower surface of the sheet, bonding performance orbonding adhesion to the light emitting element being used can beimproved. In the case where it is convex with respect to the uppersurface of the sheet, this improves the light extraction efficiency.

The light-transmissive member may have a flat shape or, for example,being intentionally machined to have a bend, curve, etc. This allows thelight-transmissive member to be thin. Alternatively, it may have theshape of a so-called micro-lens, a fly-eye lens, or the like, in whichthe upper surface of the color conversion material layer has a shapethat is textured in the thickness direction of the light-transmissivemember itself (see the light-transmissive member 10K in FIG. 8). Thisallows the light emitting device with the light-transmissive member toimprove optical coupling efficiency to a light-guide plate in the caseof being used in a backlight, for example, depending on the applicationof the light-transmissive member.

The light-transmissive member may include one color conversion materiallayer in the through-hole of on one sheet, or may include a plurality ofcolor conversion material layers are arranged in the through-holes ofone sheet so that the color conversion material layers are respectivelydisposed in the respective through-holes. A size of thelight-transmissive member in the case of disposing just one colorconversion material layer is preferably somewhat greater than the sizeof the light emitting element, etc., being used. For example, it maymeasure 0.1 to 200×0.1 to 200 mm. The size of the light-transmissivemember in the case of disposing a plurality of color conversion materiallayers can be suitably set depending on the size, number, and so forthof the color conversion material layer discussed below.

The outer peripheral portion of the color conversion material layer ofthe light-transmissive member (that is, a sheet) may be machined toprovide the through-hole or to be in a fittable shape. In the case wherethe light-transmissive member is relatively large, and/or is long andslender, it is preferable to provide a shape for positioning or fittingto other components. This allows making assembly and joining to thelight emitting device or the light emitting element discussed belowwithout any misalignment.

Sheet

The sheet is a member that supports the color conversion material layer.The sheet is light reflective. The term “light reflective” here meansthat the light reflectivity with respect to the light emitted from thelight emitting element is at least 60%, and preferably at least 70%,80%, or 90%.

Also, “light reflective sheet” includes a sheet whose material islight-reflective and a sheet where a material which is notlight-reflective is processed to be imparted with light-reflectivity.The processing to be light reflective can be performed in any step ofthe manufacturing the light-transmissive member.

That is, for the light reflective sheet, a light reflective material (afirst light reflective material) or a material that is not lightreflective, such as a light-transmissive material or a light absorbentmaterial, may be used.

Examples of the light reflective materials include metals and lightreflective substances (e.g., titanium dioxide, silicon dioxide, zincdioxide, zirconium dioxide, potassium titanate, alumina, aluminumnitride, boron nitride, mullite, niobium oxide, barium sulfate, coloringagent, and various types of rare earth oxides such as yttrium oxide,gadolinium oxide, etc.). The metal or light reflective substance mayitself be made into a sheet, or a granular material may be formed into asheet with a binder such as a resin.

For instance, the sheet can be either a single layer or a stack of ametal or a dielectric material. Further, the light reflective sheet canbe obtained by adding the above-mentioned light reflective substance inan amount of about 10 to 95 wt %, and preferably about 20 to 80 wt %,and more preferably about 30 to 70 wt %, and even more preferably about30 to 60 wt %, to a resin, an inorganic material, glass, or the like, ora composite thereof. The light reflective sheet can also be one in whichthe surface of one of these metal, dielectric, or resin sheets iscovered with a light reflective substance or a metal film (a secondlight reflective material), etc. Such an arrangement allows facilitatingto form the sheet as desired. It also allows ensuring a sufficientstrength. Furthermore, sufficient resistance can be ensured againsttemperature changes in the filling and curing of the light-transmissiveresin discussed below.

Examples of the materials of metals used for the light reflective metalfilms include single layer films or laminate films of silver, aluminum,copper, gold, platinum, palladium, rhodium, nickel, tungsten,molybdenum, chromium, titanium, and alloys of these. The material forthe metals used for the light reflective sheet is similar to these.Examples of the dielectric film include single layer film and laminatefilms that are used in this field. An example is SiO₂/Nb₃O₅ or othersuch laminate.

Examples of resins that can serve as a base material includethermosetting resins, thermoplastic resins, modified resins of theseresins, and hybrid resins that contain one or more of these resins.Specific examples of the resin includes epoxy resins, modified epoxyresins (silicone-modified epoxy resin, etc.), silicone resin, modifiedsilicone resin (an epoxy modified silicone resin, etc.), hybrid siliconeresin, a polyimide (PI), a modified polyimide resin, polyamide (PA),polyethylene terephthalate resin, polybutylene terephthalate (PBT), GFreinforced polyethylene terephthalate (GF-PET), polycyclohexaneterephthalate resins, polyphthalamide (PPA), polycarbonate (PC),polyphenylene sulfide (PPS), polysulfone (PSF), polyether sulfone (PES),a modified polyphenylene ether (m-PPE), polyether ether ketone (PEEK),polyetherimide (PEI), liquid crystal polymer (LCP), ABS resin, phenolresin, acrylic resin, PBT resin, urea resin, BT resin, a polyurethaneresin, polyacetal (POM), an ultrahigh molecular weight polyethylene(UHPE), a syndiotactic polystyrene (SPS), an amorphous polyarylate(PAR), a fluorocarbon resin, and an unsaturated polyesters.

Examples of the inorganic materials include single layer structures ormultilayered structures that contain aluminum oxide, aluminum nitride,zirconium oxide, zirconium nitride, titanium oxide, titanium nitride,zinc oxide, mixtures of these, or other such ceramics, orlow-temperature sintered ceramics, etc.

As the light transmissive material, the light transmissive material ofthe above-mentioned resin, glass, a dielectric material or the like canbe used. As the light absorbing material, ceramics described above,paper, fiber, pulp, carbon, a dielectric, a composite material such asglass epoxy or the like can be used. Light absorbing material may have alight conversion function. In the case where the light reflective sheetis formed from one of these light-transmissive materials and/or lightabsorbing materials, the light reflective characteristics that are givenduring manufacturing of the light-transmissive member are preferablyobtained by covering the inner surface of a through-hole (orthrough-holes) discussed below and a surface of the light reflectivesheet with a light reflective material. It is preferable that the entiresurfaces including the front and bark and the side surfaces is coveredby the light reflective material, but a part of the sheet may not becovered, as long as substantially the entire surfaces of the side wallsof the through-hole touching the color conversion material layer iscovered by the light reflective sheet.

The light reflective sheet may contain a diffusing agent, a lightscattering agent (such as barium sulfate, titanium dioxide, aluminumoxide, or silicon oxide), or the like. Also, any glass cloth, filler, orthe like such as glass fiber, wollastonite, and other such fibrousfillers, and carbon, silicon oxide, and other such inorganic fillersused in the field of semiconductor BGA mounting may be contained inorder to ensure good heat dissipation, strength, etc.

In particular, it is preferable for the light reflective sheet to beobtained by forming a light reflective material that contains a lightreflective substance and a resin into the light reflective sheet, sincesuch sheets are readily available.

The thickness of the light reflective sheet can be suitably setaccording to the materials being used and so forth, and it is preferablythick enough to ensure the proper strength and light reflectivity. Forexample, the thickness may be from a few dozen microns to about 1 mm,with a few dozen microns to about 500 μm being preferable, and about 100to 300 μm being even preferable.

In addition to the light reflective substance and the light transmissiveresin, the reflective sheet may also contain a light emitting material.In particular, in the case where the size of the through-hole, in whichthe color conversion material layer is disposed, is smaller than thelight emitting element, containing the light emitting material allowsreducing the escape of light (e.g., blue light) from the light emittingelement.

The size of the through-hole in plan view may be, for example, {a fewhundred microns to a few millimeters}×{a few hundred microns to a fewmillimeters}, or {a few hundred microns to 1 mm}×{a few hundred micronsto 1 mm}, or a shape with a size that corresponds to these surfaceareas. Examples of the shape of the through-hole in plan view includecircular, elliptical, polyhedral, and shapes that are approximate tothese. It is especially preferable for the plan view shape of thethrough-hole to be substantially similar to the plan view shape of thelight emitting element.

The through-hole may have the same shape and size in the thicknessdirection of the sheet, or their shape and size may vary from onesurface to the surface opposite to the one surface as shown see thelight-transmissive members 10I and 10J in FIG. 8 such as a truncatedelliptical cone or a truncated prismatic cone.

The size and shape of the through-hole may correspond to the size andshape of the color conversion material layer.

In the case where a plurality of through-holes are arranged on a singlesheet, it is preferable that they are spaced enough that the sheet willnot be broken by the arrangement of the through-holes. An example of aspacing between the through-holes is about 0.01 mm to a few millimeters.This arrangement may be random, or the through-holes may be arranged ina ring shape as shown in the light-transmissive member 100A in FIG. 9,and the through-holes are preferably arranged regularly in the row andor column direction as shown in FIGS. 1D and 2A.

Color Conversion Material Layer

The color conversion material layer is formed substantially without anyvoids in the through-hole, and the color conversion material layer ismade of a color conversion material and a cured light transmissiveresin. The color conversion material layer may also contain theabove-mentioned diffusing agent, light scattering agent, glass cloth,fillers, etc.

The color conversion material can be a material known in this field suchas yttrium-aluminum-garnet (YAG)-based phosphors activated by cerium,lutetium-aluminum-garnet (LAG)-based phosphors activated by cerium,nitrogen-containing calcium aluminosilicate (CaO—Al₂O₃—SiO₂)-basedphosphors activated by europium and/or chromium, silicate ((Sr,Ba)₂SiO₄)-based phosphors activated by europium, β-SiAlON phosphors andKSF-based phosphors (K₂SiF₆:Mn). It may also be a crystallized orsintered phosphor, a sintered composite of a phosphor and an inorganicmaterial, or the like. This allows obtaining a light emitting devicethat emits mixed color light (such as white light) that is a mixture ofprimary and secondary light of a visible wavelength, or a light emittingdevice that emits secondary light of a visible wavelength when excitedby primary light such as ultraviolet light.

Further, examples of the color conversion material include a luminescentmaterial referred to as a so called nanocrystal or quantum dot, which isnano-size high-dispersive particles of semiconductor materials, forexample group II-VI, group III-V and group IV-VI semiconductors, morespecifically ZnS, CdS, CdSe, InAgS₂, InCuS₂, core-shell typeCdS_(X)—Se_(1-X)/ZnS, and GaP. The color conversion material may alsobe, InAs InP, InAsP, InGaP, ZnTe, ZnSeTe, ZnSnP, or ZnSnP₂.

In this embodiment, a color conversion material with which there aredisadvantages in terms of heat resistance, water resistance, andenvironmental gas resistance can be used effectively. More specifically,a color conversion material that is vulnerable to heat and/or moisturegenerated by the processing involved in assembly of the light emittingdevice discussed below, such as a KSF phosphor that may be readilydegraded by water of a dicer, and quantum dots that are susceptible toheating during reflow, can be effectively used without impairing itscharacteristics, etc. That is, the light-transmissive member includingthe color conversion material can be cut in advance with a laser or thelike to adjust the size of the pieces, and these are directly fixed toindividual light emitting elements, or fixed to the light emittingelements after the light emitting devices including the light emittingelements have been mounted on a secondary mounting substrate by reflow,etc., which allows the color conversion material to be effectivelyprovided impairing its characteristics, etc.

In particular, in the case where the light emitting device is used forthe backlight of a liquid crystal display, etc., it is preferable to usea color conversion material that is excited by blue light and emits redlight (such as a KSF-based phosphor) and a color conversion materialthat is excited by blue light and emits green light (such as abeta-SiAlON phosphor). Using such materials allows for expanding thecolor reproduction range of the display in which the light emittingdevice is used. In particular, KSF has a sharper peak of the emissionspectrum than other color conversion materials which emits red colorsuch as CASN or SCASN. Thus, in the case where light is extractedthrough a color filter used in the display device, amount of red lightwith low luminosity factor can be decreased, and there will be lesslights that go through a (such as green) color filter of other color. Asa result, green light and red light of higher color purity can beobtained, and the color reproducibility of the liquid crystal displaycan be improved.

The color conversion material may be used in any form, such as apulverized form, spherical form, or hollow or porous granules. Aparticle of the color conversion material preferably has a medianparticle size of 50 μm or less, more preferably 30 μm or less, even morepreferably 10 μm or less, or a corresponding size. The median particlesize refers to a particle size obtained by an air permeability method inF.S.S.S.No (Fisher Sub Sieve Sizer's No).

The color conversion material is preferably contained in an amount ofabout 10 to 90 wt % with respect to the total weight of the colorconversion material layer.

The light-transmissive resin that constitutes the color conversionmaterial layer can be selected from among the above-mentioned resinsthat are light-transmissive resins. Of these, it is preferable to selectone with less expansion and shrinkage during curing or under temperaturechanges. Also, in the case where a resin is used as a material of thelight reflective sheet, it is preferably to use the same resin as thatof the light reflective sheet. This can ensure good adhesion between thelight-reflective sheet and the color conversion material, and allows thelight-transmissive member to be manufactured stably.

Using the light-transmissive member such as this allows for improvingvisibility of the light emitting device. That is, disposing the colorconversion material layer in the through-hole formed in the lightreflective sheet, or in other words, disposing the color conversionmaterial layer so as to be completely surrounded by the light reflectivesheet, allows for improving a distinct boundary between the lightemission region and the non-emission region of the light emitting devicesimply, easily, and precisely.

In particular, in the case of using a color conversion material thattends not to absorb light, or in which optical absorption tends todecrease, is used in the color conversion material layer, it will benecessary to increase the proportion of the color conversion material inthe color conversion material layer, or to make the color conversionmaterial layer relatively thicker in order to ensure the proper amountof the color conversion material. Even in the case where alight-transmissive resin contains a relatively large amount of the colorconversion material, or even in the case where film thickness control isrequired to ensure the proper amount of color conversion material, theabove mentioned configuration allows these requirements to be met withcase, and thus allows a high-quality light-transmissive member to beobtained, which can be used in the manufacture of a high-quality lightemitting device.

Functional Film

A processing may be performed on an upper surface and and/or a lowersurface of the light-transmissive member, and particularly on the uppersurface and/or lower surface of the color conversion material layer, toprotect from humidity and corrosive gas, or to enhance their strength,etc. More specifically, the protective processing is to dispose one ormore functional films having the function of protection,moisture-proofing, reinforcement, or the like as a single layer ormultilayered structure (see the light-transmissive member 10L in FIG.8).

For example, as long as it is light-transmissive, this functional filmcan be formed from the above-mentioned resin that constitutes the lightreflective sheet, etc. A filler or the like may be added to the resinfor the sake of reinforcement, etc. More specifically, examples includea film of Al₂O₃, SiOx, or the like with high gas barrier properties, andepoxy resins, silicone epoxy hybrid resins, fluororesins, parylene-basedgas barrier films, and so forth.

Also, the light-transmissive member, and particularly a singlelight-transmissive member having a single color conversion materiallayer, can be small, so a sheet of glass or the like may be disposed onthe upper surface of the light-transmissive member to ensure thestrength of the light-transmissive member, or the upper surface may becoated with a light-transmissive resin or the like, or furtherprocessing may be performed for the sake of reinforcement.

First Method for Manufacturing Light-Transmissive Member

The light-transmissive member can be manufactured by the followingsteps.

(a) Preparing a sheet;

(b) forming a through-hole in this sheet;

(c) imparting a light reflecting function to the sheet; and

(d) filling the through-hole with a light-transmissive resin thatcontains a color conversion material, and curing the resin to form acolor conversion material layer.

In addition, the following steps can be optionally included.

(e) Cutting the sheet for each through-hole or each group ofthrough-holes;

(f) forming a functional film; and

(g) sorting the color or light flux according to the light conversionability of color conversion material layers in the through-holes on thesheet.

(a) Sheet Preparation

First, a sheet is prepared.

The sheet here, as discussed above, may be formed from a lightreflective material, or may be formed from a material other than a lightreflective material, such as a light-transmissive material or a lightabsorbing material.

The sheet can be formed by using a method that is known in the field ofplastic molding, such as injection molding, extrusion molding, heatmolding, or compression molding.

(b) Formation of Through-Hole

A through-hole is formed in the sheet. The through-hole may be formed byusing any method known in this field. Examples of the method includelaser light irradiation or delineation, punching, stamping, etching, andblasting.

In particular, through-hole can be formed with good precision byirradiation with a laser beam. A fundamental wave, double wave, triplewave, quadruple wave, or the like of a CO₂ laser or a solid state lasercan be used for this laser. As to the wavelength, a wavelength ininfrared region is preferable.

After the formation of the through-hole, it is preferable to remove anyscorching, smears, or the like by washing.

Also, in the preparation of the sheet in step (a), the sheet preparationand the through-hole formation may be performed simultaneously, such asby using a metal mold having a recess and a protrusion that correspondsto the through-hole to form a light reflective material, alight-transmissive material, or a light absorbing material.

(c) Imparting of Light Reflecting Function to Sheet

A light reflecting function may be imparted to the sheet during theformation of the sheet, so that the sheet can be a light reflectivesheet. That is, steps (a) and (c) may be performed at the same time.Also, a light reflecting function may be imparted separately to thesheet after the through-hole have been formed (step (b)) in a sheet madeof a material other than a light reflective material.

In the case where the impaction of a light reflecting function to thesheet is performed simultaneously with the formation of the sheet, thenthe sheet should be formed from a light reflective material (the firstlight reflective material), as discussed above. In this case, forexample, a method in which a metal or a dielectric material is formed asthe sheet, a method in which a material containing one of theabove-mentioned light reflective substances in a light-transmissiveresin, an inorganic material, glass, or the like is molded in the formof a sheet, or a method in which the surfaces of the metal or dielectricmaterial, or the sheet including the above-mentioned light reflectivesubstances in a light-transmissive resin are covered by a metal or alight reflective substance can be used.

In the case where a light reflecting function is imparted to the sheetafter the formation of the through-hole, an example of how this isperformed includes to cover the surface of the sheet and the innersurfaces of the through-hole with a light reflective material by anymethod known in this field, such as plating, various kinds of molding,spraying, injection, vapor deposition, inkjet printing, or by using ALDmethod. The light reflective material used for the covering ispreferably as thin as possible. The thickness of the light reflectivematerial covering is, for example, preferably equal to or less thanabout a few dozen microns.

Even in the case where the formation of reflective side walls of thelight emitting device is physically difficult due to the small size ofthe light emitting device, utilizing the sheet to which a lightreflecting function can be easily imparted allows to introduce ordistribute the light from the light emitting device to where it isneeded. As a result, the light utilization efficiency can be increased.

(d) Formation of Color Conversion Material Layer

The insides of the through-hole are filled with a light-transmissiveresin that contains a color conversion material, and this resin is curedto form a color conversion material layer.

Any method known, in this field can be used to fill the through-holewith the light-transmissive resin that contains a color conversionmaterial, such as potting, molding, printing, spraying, and variousother such methods. In this step, the filling is preferably performed sothat after the light-transmissive resin is cured, the upper surface ofthe color conversion material layer will be in the same plane with theupper surface of the light reflective sheet.

The curing of the light-transmissive resin can be suitably set accordingto the type of resin being used. Examples include a method of leavingthe resin is allowed to stand for a specific length of time, a method ofblowing cold air against the resin, a method of heating the resin (veryapproximately from around several dozen ° C. up to around a hundred andseveral dozen ° C.), and a method of irradiating the resin with anenergy beam (X rays, ultraviolet rays, visible light rays, etc.).

When a plurality of color conversion material layers are formed on asingle sheet, the same color conversion material need not be used forall of the color conversion material layers, and a number of differentcolor conversion materials may be used. In this case, RGB color emissioncan be achieved using a single light-transmissive member by regularlyarranging the layers for each color of the color conversion materials.

(e) Cutting of Sheet

In the case where a plurality of through-holes are thrilled in the sheetin step (a), and a plurality of color conversion material layers areformed in step (d), the light reflective sheet may be cut after step(d). The cutting of the sheet may be performed in any way as long as asheet, and particularly a light reflective sheet, is disposed aroundsubstantially the entire outer periphery of the color conversionmaterial layer.

The cutting may be performed so that one color conversion material layeris disposed in one sheet. For example, the light reflective sheet may becut to a size of about a few tenths of a micron to a few millimeters.

Also, the light reflective sheet may be cut so that a plurality of colorconversion material layers are disposed in a single light reflectivesheet. In this case, for example, it is preferable for the colorconversion material layers to be cut so that the plurality of colorconversion material layers in groups of about 5 to 20, and morepreferably in groups of about 7 to 15, and even more preferably ingroups of about 8 to 12, are disposed in the single light reflectivesheet. These color conversion material layers are preferably arranged ina single row, and the light reflective sheet is cut, for example, to alength of about a few tenths of a micron to 5 cm, and preferably about afew tenths of a micron to a few centimeters.

The cutting method can be suitably selected depending on thecharacteristics of the color conversion material, filler, and resinmaterial being used. This cutting can be performed by any sheet cuttingmethod known in this field, such as blade dicing, laser dicing, orcutter scribing. For instance, in the case of using a color conversionmaterial that is not resistant to moisture, it is preferable to selectlaser dicing. In the case of using a color conversion material that isnot resistant to heat, it is preferable to select blade dicing. In thecase where the material is resistant to neither moisture nor heat, thecolor conversion material can be prevented from being directly exposedto moisture and/or heat, as long as the color conversion material layeris not cut directly. Also, since the light-transmissive member is in theform of a sheet, additional processing of a protective film or othersuch functional film can be easily carried out.

Second Method for Manufacturing Light-Transmissive Member

The light-transmissive member can also be manufactured by the followingsteps.

(d′) A color conversion material layer is formed by curing alight-transmissive resin that contains a color conversion material; and

(a′) a resin layer having a light reflecting function is formed as asheet or a multilayered structure on the outer peripheral side surfaceof the color conversion material layer.

(d′) Formation of Color Conversion Material Layer

In the formation of the color conversion material layer, the materialthat forma the above-mentioned color conversion material layer is formedas islands on a support sheet by potting, printing, spraying, or any ofvarious other such methods. To form the color conversion material layerin the islands shape, a mask or the like having openings at the siteswhere the color conversion material layer is to be formed can beutilized. A self-alignment effect can also be used, which takesadvantage of hydrophilicity and water repellency between the materialfor the color conversion material layer and the support sheet. Just onecolor conversion material layer may be formed, or two or more may beformed. In the case of forming more than one color conversion materiallayers, the color conversion material layers are preferably formedseparated from one another.

(a′) Formation of Sheet

The material constituting the above-mentioned sheet can be used as thematerial that constitutes the resin layer to be made in the form of asheet-like shape or a multilayered structure. This material is, forexample, melted or dissolved in a solvent to be fluid, and then isformed into a sheet-like shape or a multilayered structure so as tosurround the side surface of the color conversion material layer. Theside surface of the color conversion material layer here is preferablysurrounded entirely.

In the case where a plurality of color conversion material layers areformed in the previous step, the entire outer peripheral side surface ofthe light reflective sheet is preferably formed integrally with some orall of these color conversion material layers.

The material constituting the above-mentioned resin layer is preferablythe above-mentioned light reflective material, but it is sufficient thata light reflecting function is imparted to the resin layer in the end.For imparting light reflectivity, in the case where a material which isnot light reflective is used as the material that forms the resin layer,for example, then as mentioned above, it is preferable for the sidesurface, and preferably the entire side surfaces of the resin layer tobe covered with a metal or another light reflective substance by anymethod known in this field, such as plating, spraying, vapor deposition,printing, or ALD.

For example, in the case where spraying is performed, a silicone resincontaining a high concentration of titanium dioxide is sprayed directlyonto a color conversion material layer made in the island shape, afterwhich a silicone resin containing a low concentration of titaniumdioxide may be subjected to compression molding and may be made into asheet. Optionally, a surface of the side that has been sprayed withtitanium dioxide may be ground with a grinder to remove the layercontaining the titanium dioxide. That is, a resin layer having a lightreflecting function may be formed as a multilayered structure on theouter peripheral side surface of the color conversion material layer.

Except for above-mentioned steps, all the steps can be performed in away similar to the first method for manufacturing a light-transmissivemember, and optional steps as below may be added.

(f) Formation of Functional Films

Further, the above-mentioned functional films may be formed. These filmscan be formed by using ALD method, sputtering, vapor deposition, CVD, oranother such method.

(g) Sort According to Color or Light Flux

An optical conversion performance of the color conversion material layerformed in the through-hole may be measured to be sorted according tocolor or light flux. After sorting, the sorted light-transmissive membercan be mounted on a light emitting element that emits light of aparticular wavelength, in a state in which the light-transmissive memberhas been made into individual units or not-individualized unit, eitherbefore or after step (e). Consequently, a higher yield of the lightemitting device can be anticipated, especially in the case where thelight flux or color is measured in a slate before individualization inadvance.

Method for Manufacturing Light Emitting Device

The light emitting device can be formed by:

(A) fixing the above-mentioned light-transmissive member on a lightemitting element so that the color conversion material layer is disposedon the light emitting element; and

(B) covering side surfaces of the light emitting element with a lightreflective member.

Steps (A) and (B) are preferably performed in the above order, but mayinstead be performed simultaneously or in reverse order. Also, a lightemitting element may preferably be mounted on the substrate of the lightemitting device before or after step (A), and particularly preferablebefore step (A). A single light emitting element may be mounted on asingle substrate, or a plurality of light emitting elements may bemounted on a plurality of substrates, or a plurality of light emittingelements may be mounted on a single substrate.

Furthermore, in case where a plurality of light emitting elements aremounted on a single substrate, a step of separating them for each lightemitting device or a group of light emitting devices may be performedafter step (B). That is, the light emitting element whose side surfacesare covered by a light reflective member, or the light emitting elementand the light-transmissive member, whose side surfaces are covered by alight reflective member may be made into individual units.

The damage on the color conversion material, etc., in the assemblyprocess of the light emitting device can be minimized in the case wherestep (B), the step of separation by light emitting device, and step (A)are performed in that order.

As discussed below, the light emitting element used here may be mountedon a substrate with terminals.

(A) Fixing of Light-Transmissive Member and Light Emitting Element

The light-transmissive member formed by the method discussed above isfixed to the upper surface of the light emitting element. That is, thelight-transmissive member is disposed on the light extraction surfaceside of the light emitting device. A portion of the upper surface of thelight emitting element is preferably in direct contact with thelight-transmissive member, and more preferably is firmly adhered to thelight-transmissive layer.

There may be just one, or two or more of the light-transmissive membersused in this step. Also, there may be just one, or two or more of thelight emitting elements used in this step. That is, the light emittingdevice manufactured in this method may include just one light emittingelement, or may include two or more. A configuration such as this allowsthe number of the light emitting elements and the combination ofturned-on/turned-off of the light emitting elements to be selected, andallows light distribution and emission color of the light emittingdevice to be controlled in various ways.

A single light-transmissive member may be fixed to the upper surface ofa plurality of light emitting elements, but from the standpoint ofensuring good visibility, it is preferable that a singlelight-transmissive member, and particularly a single color conversionmaterial layer, is fixed on a single light emitting element. This caneffectively prevents light from leaking in unintended directions fromthe light emitting element. As a result, visibility can be furtherimproved in individual light emitting elements by the simplemanufacturing method discussed above.

Also, in the case where a plurality of light emitting elements aremounted on a substrate, a light-transmissive member on which a pluralityof color conversion material layers are disposed at positionscorresponding to the light emitting elements are preferably fixedcollectively on these light emitting elements.

The light emitting element used here can be any light emitting elementthat is commonly used in this field. Examples of blue and green lightemitting elements include those made of ZnSe, nitride semiconductors(In_(X)Al_(Y)Ga_(1-X-Y)N, 0≤X, 0≤Y, X+Y≤1), GaP, or other suchsemiconductor layers, while examples of red light emitting elementsinclude those made of GaAlAs, AlInGaP, and other such semiconductorlayers.

The light emitting element is can be formed by stacking a semiconductorlayer over an insulated substrate used for semiconductor growth, such assapphire, but this semiconductor growth substrate may also be removedduring forming of the light emitting element.

The light emitting element may be one in which electrodes are disposedon opposite sides of the semiconductor layer, but is preferably one inwhich the electrodes are disposed on the same side. This allows forface-down mounting (flip-chip mounting) in which the electrodes arejoined to the substrate. The light emitting element may have a face-downstructure that has a growth substrate, a face-down structure that doesnot have a growth substrate, a face-up structure that has a growthsubstrate, a face-up structure that does not have a growth substrate, orthe like.

The light emitting element is preferably one that is the same size orsmaller than an area defined by outer edges of the color conversionmaterial layer in plan view as shown in FIG. 5C. This allowssubstantially all of the light emitted from the light emitting elementto be efficiently introduced into the color conversion material layer,and thus allows improving of the light extraction of the light emittingdevice. The light emitting element may be also one that is the same size(the outer edges substantially coincide) or larger than the outer edgeof the color conversion material layer. Also in this case, covering theside surfaces of the light emitting element with a light reflectivemember (discussed below) allows a light emitting device with goodvisibility, uniform emission color, and good light distribution andcolor to be formed.

A light emitting element 14 is preferably smaller, than the outer edgeof a light-transmissive member 10, as shown in FIG. 5C and FIGS. 12A to12C. This allows the outer edge of the light-transmissive member to bedisposed outside of the outer edge of the light emitting element, andallows a light emitting device with good visibility, uniform emissioncolor, and good light distribution and emission color to be formed. Thethrough-hole in which the color conversion material layer is disposedmay be either tapered or reverse tapered from the element side towardthe light extraction surface as shown in FIGS. 12B and 12C.

Furthermore, a light emitting element that is larger than the outer edgeof the light-transmissive member in plan view may be used. In this case,the side surfaces of the light emitting element and the upper surface ofthe light emitting element (and optionally the side surfaces of thelight-transmissive member) are covered by the light reflective memberdiscussed below, which allows a light emitting device with goodvisibility, high brightness, uniform emission color, and good lightdistribution and color temperature to be formed. The through-hole inwhich the color conversion material layer is disposed is preferablyreverse tapered, that is, a width of the through-hole is decreased fromthe element side toward the light extraction surface.

The fixing of the light transmissive member to the upper surface of thelight emitting element can be accomplished by using a light-transmissiveadhesive member, for example. Any adhesive member can be used, so longas it ensures the above-mentioned light-transmissivity and can fix thelight-transmissive member to the light emitting element. A material thatis not readily degraded by light is preferable as the light-transmissiveadhesive member. Examples of the material include silicone adhesives,epoxy adhesives, and silicone-epoxy hybrid adhesives.

The color conversion material layer or sheet surface can be utilized asthe adhesive member itself. That is, the color conversion material layeror the light reflective sheet itself may be given adhesive properties,or the adhesion of the color conversion material layer or sheet may beutilized.

The adhesive member can be formed in a fillet shape that expands fromthe outer edge of upper surface of the light emitting element to thelower surface of the outer edge of the light-transmissive member in thecase of using a light emitting element whose outer edge is smaller thanthat of the light-transmissive member in plan view. Also, the adhesivemember can be formed in a fillet shape that expands from the outer edgeof the lower surface of the light-transmissive member to the outer edgeof the upper surface the light emitting element in the case of using alight emitting element whose outer edge is larger than thelight-transmissive member in plan view. From the standpoint of forming alight emitting device with good visibility, it is preferable for theouter edge of the adhesive member to be disposed more to the inside thanthe outer edge of the light-transmissive member, or for the outer edgeof the adhesive member to be covered by a light reflective member, asdiscussed below.

The light-transmissive member may also be mounted mechanically on thelight emitting element by utilizing a processed surface, texturing onthe light reflective sheet that is simultaneously processed in theformation of the above-mentioned through-holes, or the like to fit,partially bond, etc., to the structure of the light emitting element,the light emitting device, and a light source or other such device thatemits light.

As discussed above, the light emitting element is preferably mounted ona substrate. There are no particular restrictions on the substrate here,which may be a substrate having a pair of positive and negativeterminals for mounting a single light emitting element, or may be asubstrate having a wiring pattern for mounting a plurality of lightemitting elements.

the substrate include, for example, an insulated base, on the surface ofwhich are formed conductive terminals or a wiring pattern. The materialsthat form the base and the terminals or the wiring pattern, their shape,size, and so forth can be suitably selected according to theconfiguration of the light emitting device to be obtained.

The light emitting element may be mounted in the face-up mounting, inwhich the growth substrate side of the light emitting element theopposite side from the side where the electrodes are formed) is joinedon the substrate, but flip chip mounting (face down mounting) on thesubstrate is preferable.

In the case of face-up mounting, for example, the above-mentionedlight-transmissive adhesive member (resin, etc.) can be disposed on thelight emitting element so that a portion of the wires is embedded andthe light-transmissive member is disposed over this. Also, as will bediscussed below, a side surface of a light-transmissive part of thelight emitting element, such as sapphire, can be covered with a lightreflective member in step (C) and before the mounting of thelight-transmissive member in order to improve light extraction from theupper surface of the light emitting element. A made of transparentmaterial with a tapered shape may be provided between thelight-reflective member and the transparent the light-transmissive partof the light emitting element.

The light emitting element can be mounted on the substrate via a joiningmember. Examples of the joining member here include solders such asthose based on tin-bismuth, tin-copper, tin-silver, gold-tin, or thelike; alloys whose main components are gold and tin, alloys whose maincomponents are gold and germanium, and other such eutectic alloys;silver, gold, palladium, and other such conductive pastes and bumps;ACP, ACF, and other such anisotropic conductive materials low-meltingpoint metal brazes; conductive adhesives that are a combination ofthese; and conductive composite adhesives.

In the case of flip-chip mounting, the electrodes of the light emittingelement can be directly connected to the wiring pattern of the substratevia these materials.

In the case where one or a plurality of light emitting elements aremounted on a plurality of substrates, a plurality of light-transmissivemembers may be arranged on a single support prior to step (A), orinstead of this arrangement, a light-transmissive member equipped with aplurality of color conversion material layers may be used.

As the support, it is preferable to use a detachable pressure-sensitiveadhesive tape or sheet, a temporary fixing agent for a semiconductor, apatternable temporary fixing agent, or the like. Using the supportallows the plurality of light-transmissive members to be simultaneouslymounted on and fixed to the plurality of light emitting elements. As aresult, the manufacturing process can be simplified. The manufacturingprocess can also be simplified by using a light-transmissive memberincluding a plurality of color conversion material layers.

A printed wiring board, a printed circuit board, or the like includingwirings wired for the mounting of an LED, ZD, or any of various othercomponents for lighting applications that can actually it used as alight source, can also be used as the support.

(B) Covering with Light Reflective Member

The side surfaces of the light emitting element are covered with a lightreflective member.

The light reflective member can be made of the light reflectivematerials discussed above. In particular, in terms of simplicity andease of covering, it is preferable to use a light reflective substancecontained in a resin or an inorganic material. The resin can be selectedfrom among the above-mentioned thermosetting resins, thermoplasticresins, modified resins of these, and hybrid resins that contain one ormore of these resins. Of these, the use of a light-transmissive resin ispreferable, and from the standpoint of adhesion to thelight-transmissive member, etc., it is preferable to use the resin thatconstitutes the light-transmissive member, and particularly a resin thatis the same as the material constituting the light reflective sheet.

As long as it covers the side surfaces of the light emitting element,the light reflective member may cover indirectly, via a space, etc., butis preferably disposed directly, that is, so as to be in contact withthe side surfaces of the light emitting element. Covering in this wayallows the light emitted from the light emitting element to bedistributed more efficiently in a particular direction.

The side surfaces of the light emitting element that are covered may bejust some of these surfaces, but are preferably all the side surfaces.The phrase “side surfaces of the light emitting element” here means, forexample, the side surfaces of the semiconductor layer constituting thelight emitting element, but in the case of disposing electrodes, thenthe light reflective member may be disposed on the side surfaces of theelectrodes.

Also, as discussed above, since the light emitting element can bemounted on a substrate, and in that case, the light reflective memberpreferably covers the side surfaces of the light emitting element and asurface of the substrate. Furthermore, in the case where there is aspace between the semiconductor layer and the substrate, then this spacemay be covered or filled in by the light reflective member. At all ofthese locations (that is, the side surfaces of the semiconductor layer,the electrode side surfaces, and between the semiconductor layer and thesubstrate), the same material or different materials may be used as thelight reflective member.

In the case of using a material that is the same as the materialconstituting the above-mentioned light-transmissive member as the lightreflective member, the side surfaces of the light emitting elements canbe covered by using a method such as potting, transfer molding,compression or molding. These methods can facilitate to cover the sidesurfaces of the light emitting element. Also, the light reflectivemember can be easily, securely, and accurately disposed only under thelight-transmissive member. In particular, in the case of performing step(B) after step (A), the side surfaces, of the light emitting element canbe covered by the light reflective member so that the upper surface ofthe light reflective member and the lower surface of thelight-transmissive member coincide easily and securely.

Also, the side surfaces of the light emitting element and the sidesurfaces of the light-transmissive member can be covered so that theupper surface of the light reflective member coincides with the uppersurface of the light-transmissive member.

In the case where a material that is the same as the materialconstituting the above-mentioned light-transmissive member (such as aresin same as the resin used for the light-transmissive member) is usedas the light reflective member, these light emitting elements can besimply covered all at once and integrally by the light reflective memberon the substrate on which the light emitting elements are arranged.

A molded article in which the location corresponding to the lightemitting element is hollow may be used as the light reflective member.In this case, the light reflective member with a form of the moldedarticle may be disposed on the substrate in advance, after which a lightemitting element to which a light-transmissive member has been fixed maybe disposed on the light reflective member and pressure, applied so thatthe electrodes of the light emitting element come into contact with thewiring of the substrate. The molded article preferably has a heightcorresponding to the height of the light emitting element. This allowsfacilitating to cover the side surfaces of the light emitting element bythe light-reflecting member, and also allows the light reflective memberto be disposed easily, securely, and accurately only below the lighttransmissive member (that is, without covering the side surfaces of thelight-transmissive member). Also, the upper surface of the lightreflective member can be easily and securely made to coincide with thelower surface of the light-transmissive member. In this case, step (B)can be performed before step (A).

The molded article is preferably fixed to the above-mentioned substratewith an adhesive agent or the like.

After step (B), the light-transmissive member, the light reflectivemember, and/or the substrate, etc., may or may not be separated for eachlight emitting element or for each group of light emitting elements, ifneeded, in the case where a plurality of light emitting elements aremounted on a single substrate, in the case where a singlelight-transmissive member is fixed on a plurality of light emittingelements, in the case where a plurality of light-transmissive membersare fixed on a corresponding plurality of light emitting elements, or inother such cases. This allows obtaining a light emitting device withdesired light distribution, brightness, size, and so on. The separationin this case can be performed by using blade dicing, laser dicing, orthe like.

Light Emitting Device

The light emitting device according to an embodiment of the presentinvention mainly includes a light emitting element, a light-transmissivemember, and a light reflective member.

The light-transmissive member can be the one discussed above, and isfixed on the light emitting element so that the color conversionmaterial layer is disposed on the light emitting element. The colorconversion material layer is preferably in contact with a portion of theupper surface of the light emitting element, and more preferably isfirmly adhered.

The outer edge of the light emitting element preferably either coincideswith the outer edge of the color conversion material layer in plan view,or is disposed on the inside of the color conversion material layer.

In the case where a single light emitting device includes a plurality oflight emitting elements, a light reflective sheet including a pluralityof color conversion material layers can be used as thelight-transmissive member so that the plurality of light emittingelements are collectively configured by this light-transmissive member.

In a single light emitting device, there may be just one light emittingelement or an arrangement of two or more light emitting elements. In thelatter case, it is preferable that the light-transmissive memberincludes a plurality of color conversion material layers, and the colorconversion material layer are disposed at positions corresponding to thelight emitting elements, and fixed on the light emitting elements. Thisallows to obtain a light emitting device with good visibility. Also, thecolor conversion material layers may contain the same color conversionmaterial, or may contain different color conversion materials.

The light emitting element may be mounted on a substrate on whichterminals are formed, or may not be mounted. For example, in the casewhere a single light emitting device includes a plurality of lightemitting elements, the light emitting elements can be collectivelyconfigured by the substrate on which the terminals are formed.

The upper surface of the light reflective member may coincide with thelower surface of the light-transmissive member, or it may coincide withthe upper surface of the light-transmissive member so that the sidesurfaces of the light-transmissive member are also covered.

Also, in the case where a single light emitting device includes aplurality of light emitting elements, the light emitting elements can becollectively configured by a light reflective member substrate.

A configuration such as this allows a light emitting device to beobtained extremely simply and easily, and very accurately.

In particular, in the case where a color conversion material that tendsnot to absorb light, or in which optical absorption tends to decrease,or the like is used in the color conversion material layer of thelight-transmissive member, it will be necessary to increase theproportion of color conversion material in the color conversion materiallayer, or to make the color conversion material layer relatively thickerin order to ensure the proper amount of color conversion material. Evenin the case where a light-transmissive resin contains a relatively largeamount of color conversion material, and even in the case where filmthickness control is required to ensure the proper amount of colorconversion material, these requirements can be met with ease, and ahigh-quality light emitting device can be obtained.

The light-transmissive member and the light emitting device according toembodiments of the present invention, and their methods of manufacture,will be described below in detail.

Embodiment 1: Light-Tranmissive Member and Method for Manufacturingthereof

First, a light reflective sheet 11 is prepared as shown in FIG. 1A.

The light reflective sheet 11 is made of a silicone resin that contains60 wt % TiO₂, which is a light reflective substance, and is formed intoa sheet with a thickness of 200 μm.

A plurality of substantially rectangular through-holes 11 a that measure1.1×0.2 mm are arranged in a row and column on this light reflectivesheet 11.

Next, as shown in FIG. 1B, the through-holes 11 a are filled by pottingwith a slurry obtained by mixing 18 wt % KSF phosphor with a particlesize of about 20 μm, 26 wt % beta-SiAlON with a particle size of about12 μm, and 56 wt % light-transmissive resin (silicone resin), and themixture is cured. The curing of the light-transmissive resin isaccomplished by heating at 150° C. for 240 minutes in an oven. Thisforms a color conversion material layer 12. This color conversionmaterial layer 12 is substantially flush with the light reflective sheet11, with almost no depression in the center of the through-holes 11 a.

As shown in FIG. 1C, the light reflective sheet 11, including the colorconversion material layer 12, is cut in the lengthwise direction X ofthe light reflective sheet, which gives a light-transmissive member 100in which five color conversion material layers 12 are arranged in a rowas shown in FIG. 2A, for example.

As shown in FIG. 1D, this member can also be cut in the direction Y,perpendicular to the lengthwise direction X, to form individuallight-transmissive members 10 that each have one color conversionmaterial layer 12 as shown in FIG. 2B. This individuallight-transmissive member 10 is rectangular in top view, measuring1.8×0.3 mm, for example.

The cutting here is performed with a dicer with a reduced amount ofwater usage.

In this light-transmissive member 1 the upper surfaces of the lightreflective sheet and the color conversion material layer are flush, thatis, there is no step between the two upper surfaces. With thisstructure, the dimensions of the color conversion material layer, and inturn those of the light-transmissive member, can be stabilized, and theycan be better assembled to other members.

Modification Example 1: Light-Transmissive Member

As shown in FIG. 9, instead of the light-transmissive member 100 shownin FIG. 2A, a plurality of color conversion material layers 12X may bearranged in a ring shape on a single light reflective sheet 11X.

Modification Example 2: Light-Transmissive Member

Instead of the light-transmissive member 10 shown in FIGS. 2B and 2C,color conversion material layers 12A to 12H and 12M may be concaveand/or convex with respect to the upper surface and/or lower surface ofthe light reflective sheet as with the light-transmissive members 10A to10H and 10M shown in FIG. 8. In the case where the upper surface and/orlower surfaces of the color conversion material layer is concave withrespect to the upper surface and/or lower surface of the lightreflective sheet, light convergence or other such effects can beexhibited. Also, in the case where the upper surfaces and/or lowersurfaces of the color conversion material layers are convex with respectto the upper surface and/or lower surface of the light reflective sheet,an adhesion the light emitting elements being used can be improved.Furthermore, in the case where the shape is convex with respect to theupper surface of the light reflective sheet, light extraction efficiencycan be enhanced.

In particular, in the case where the upper surfaces and/or lowersurfaces of the color conversion material layers of thelight-transmissive member have a curved surface, this is advantageousfor use in light-transmissive members with a large surface area and alinear light source.

Modification Example 3: Light-Transmissive Member

As shown by the light-transmissive members 10I and 10J in FIG. 8,through-holes 11 aI and 11 aJ of a sheet 111 have a shape that is eithertapered or reverse tapered from the surface of the light reflectivesheet to the lower surface.

Modification Example 4: Light-Transmissive Member

As shown by the light-transmissive member 10K in FIG. 8, the uppersurface of the color conversion material layer 12K may have recesses andprotrusions in the thickness direction of the light-transmissive member10K itself that is, a shape of a so-called fly-eye shape, etc. Thisallows optical coupling efficiency with a light guide plate to beimproved, depending on the application of the light-transmissive member,such as a use in a backlight.

Modification Example 5: Light-Transmissive Member

As shown by the light-transmissive member 10L in FIG. 8, a moisturebarrier film may be disposed on the upper surface of thelight-transmissive member, for example. As shown by thelight-transmissive member 10N in FIG. 8, a transparent film may bedisposed on the upper surface, for example. This allows preventingdegradation of the characteristics of the light-transmissive member inthe case of using a color conversion material that becomes brittle whenexposed to moisture, or a color conversion material that tends toreadily absorb moisture.

Embodiment 2: Light-Transmissive Member and Method for Manufacturingthereof

First, as shown in FIG. 3A, a sheet 21 that is made of glass epoxyprepreg and has a thickness of 200 μm is prepared. Substantiallyrectangular through-holes 21 a measuring 1.1×0.2 mm are formed in thissheet 21 by laser processing in a row and column, and desmearing isperformed.

Then, as shown in FIG. 3B, the sheet 21 having the through-notes 21 a isimmersed in a primer liquid containing palladium microparticles, forminga platable seed layer over the entire sheet surface, after which this issubjected to electroless nickel plating and electrolytic silver platingto form a silver film with a thickness of about a few microns. The“entire sheet surface” here refers to substantially all the sidesurfaces and the front and back surfaces of the sheet 21 and the innersurfaces of the through-holes 21 a.

Then as shown in FIG. 3C, the through-holes 21 a are filled by pottingwith a slurry obtained by mixing 20 wt % KSF phosphor with a particlesize of about 20 μm, 30 wt % beta-SiAlON with a particle size of about12 μm, and 50 wt % light-transmissive resin (silicone resin), and themixture is cured. Accordingly, a color conversion material layer 12 isformed. This color conversion material layer 12 is substantially flushwith the light reflective sheet 21, with almost no depression in thecenter of each of the through-holes 21 a.

As shown in FIG. 3D, the light reflective sheet 21, including the colorconversion material layer 12, is cut in the lengthwise direction X ofthe light reflective sheet, and in the direction Y, perpendicular to thelengthwise direction X, to form individual light-transmissive members 20that each have one color conversion material layer 12 as shown in FIG.4. A light reflective film made of silver is formed on the front andback surfaces of this light-transmissive member 20 and on the innersurface of the through-hole 21 a.

Modification Example 6: Method for Manufacturing Light-TransmissiveMember

As shown in FIG. 10A, color conversion material layers 42 are formed ona support sheet 40, for example. In the present modification example, aplurality of color conversion material layers 42 are formed, and thecolor conversion material layers 42 are formed in island shapes that areseparated from one another.

Next, as shown in FIG. 10B, a light reflective resin layer 41 that ismade of a silicone resin that contains 60 wt % TiO₂, which is a lightreflective substance, is compression molded, for example, so as to coveronly the entire side surfaces of the color conversion material layers42. After this, the light-transmissive member 100 can be obtained byremoving the support sheet 40. Other than the above, thelight-transmissive member is manufactured by the same method as inEmbodiment 1. With this method, similar effect as the method formanufacturing a light-transmissive member in Embodiment 1 can beobtained.

Modification Example 7: Method for Manufacturing Light-TransmissiveMember

As shown in FIG. 10A, color conversion material layers 42 are formed onthe support sheet 40, after which masks 44 are formed on the uppersurfaces of the color conversion material layers 42 as shown in FIG.11A. Then, a light reflective film 43 is formed on the color conversionmaterial layers 42 via these masks 44. As the light reflecting film 43,a film consisting of a silicone resin that contains 80 wt % TiO₂, whichis a light reflective substance, is formed by spraying, for example.

After this, as shown in FIG. 11B, the masks 44 and the light reflectivefilm 43 formed over them are removed by blasting, etc., to expose theupper surfaces of the color conversion material layers 42.

As shown in FIG. 11C, a light reflective resin layer 41 consisting of asilicone resin that contains 30 wt % SiO₂, which is a light reflectivesubstance, is formed between the color conversion material layers 42 soas to cover the side surfaces of the color conversion material layers42.

A light-transmissive member 100B can then be obtained by removing thesupport sheet 40. In the light-transmissive member 100B, the lightreflective film 43 is disposed on one surface of the light reflectiveresin layers 41 between the color conversion material layers 42, andwith the entire side surfaces of the color conversion material layers42.

Other than the above, the light-transmissive member is manufactured bythe same method as in Embodiment 1 and Modification Example 7. With thismethod, an effect similar to that with the method for manufacturing alight-transmissive member in Embodiment 1 and Modification Example 7.

Embodiment 3: Light Emitting Device and Method for Manufacturing thereof

First, as shown in FIG. 5A, the light emitting element 14 is mounted inface-down mounting on a substrate 16 using solder. The size of the lightemitting element 14 is 1100×200×300 μm, for example. The outer shape ofthe upper surface of the light emitting element 14 has the same size asor slightly smaller than that of the outer shape of the color conversionmaterial layer 12 of the light-transmissive member 10.

As shown in FIG. 5B, the light-transmissive member 10 obtained inEmbodiment 1 is disposed on the upper surface of the light emittingelement 14, and fixed with a light-transmissive adhesive member. Thelight-transmissive member 10 is fixed on the light emitting element 14so that the outer edge of the color conversion material layer 12 will bedisposed slightly to the outside of the outer edge of the light emittingelement 14.

As shown in FIG. 5C, a light reflective member 15 in a form of liquid isthen deposited below the light-transmissive member 10, and its fluidityis utilized to cover the entire side surfaces of the light emittingelement 14 with the light reflective member 15.

The light reflective member 15 is made of a silicone resin that contains2 to 2.5 wt % silica and 40 to 50 wt % titanium oxide.

The light reflective member 15 is disposed only under thelight-transmissive member 10, and its upper surface coincides with thelower surface of the light-transmissive member 10. The light reflectivemember 15 also covers or fills the space between the light emittingelement 14 and the substrate 16. With this structure, the light emittedfrom the light emitting element 14 toward the substrate 16 can be guidedto the light-transmissive member 10 that is not covered by the lightreflective member 15. As a result, a light emitting device with goodvisibility can be obtained.

Embodiment 4: Light Emitting Device and Method for Manufacturing thereof

First, as shown in FIG. 6A, the light-transmissive member 100 obtainedin Embodiment 1, including a plurality of color conversion materialslayers 12 as shown in FIG. 2A, is prepared.

Then, as shown in FIG. 6B, a plurality of the light emitting elements 14are mounted in a regular arrangement on a substrate 36 so as tocorrespond to the positions of the color conversion material layers 12of the light-transmissive member 100.

Next, as shown in FIG. 6C, the light-transmissive member 100 is disposedon the light emitting elements 14, and fixed, so that the outer edges ofthe color conversion material layers 12 will be disposed to the outsideof or coincide with the outer edges of the light emitting elements 14.

Then, as shown in FIG. 6D, the light reflective member 15 in a form ofliquid is deposited under the light-transmissive member 100 and betweenthe light-transmissive member 100 and the substrate 36 to integrallycover the entire side surfaces of the light emitting elements 14utilizing the fluidity of the light-reflective member 15.

This allows a light emitting device to be obtained in which five lightemitting elements are arranged in a row.

As shown in FIG. 6E, the light reflective sheet 11 of thelight-transmissive member 100, the light reflective member 15, and thesubstrate 36 are cut at cutting positions C by a dicer so that the sidesurfaces of the light reflective member 15 will be exposed, and thus anindividualized light emitting device with a light emitting element canbe obtained.

The manufacturing method discussed above allows a light-transmissivemember and a light emitting device to be manufactured easily andaccurately.

Also, regardless of the number of light emitting elements mounted, theresulting light emitting device can distribute the light emitted fromthe individual light emitting elements to the light extraction surface.This makes it possible to obtain alight emitting device with bettervisibility.

Embodiment 5: Light Emitting Device and Method for Manufacturing thereof

First, as shown in FIG. 7A, a plurality of light emitting elements 14are arranged in a regular pattern on a substrate 36.

As shown in FIG. 7B, the light-transmissive members 20 each including aplurality of color conversion material layers as shown in FIG. 4 andobtained in Embodiment 2 are prepared, at positions corresponding to thelight emitting elements 14 arranged on the substrate 36, on a detachablepressure-sensitive adhesive sheet serving as at support 37. The colorconversion material layers 12 in the present embodiment may contain thesame color conversion material, or may contain different colorconversion materials.

As shown in FIG. 7C, the light-transmissive members 20 are mountedcollectively on the light emitting elements 14, and fixed collectively,so that the outer edges of the color conversion material layers 12 aredisposed to the outside of the outer edges of the light emittingelements 14.

Then, as shown in FIG. 7D, with the light transmissive members stillattached to the support 37, the light reflective member 15 is dischargedunder the light-transmissive members 20 to integrally cover the entireside surfaces of the light emitting elements 14 utilizing the fluidityof the light reflective member 15. In this case, under thelight-transmissive members 20, the lower surfaces of thelight-transmissive members 20 coincide with the upper surface of thelight reflective member 15 under the light-transmissive members 20. Onsides of the light-transmissive members 20, the upper surfaces of thelight-transmissive member 20 coincide with the upper surface of thelight reflective member 15.

After this, as shown in FIG. 7E, the support 37 is removed from thelight-transmissive members 20. With this, the support 37 serves as amask for the light reflective member 15, and the light reflective member15 can be disposed mainly under the light-transmissive members 20.

Then, as shown in FIG. 7E, the substrate 36 and the light reflectivemember 15 are cut with a dicer at the cutting positions C between thelight emitting elements 14 so that the side surfaces of the lightreflective member 15 will be exposed, so that an individualized a lightemitting device is obtained.

Other than the above, the method is substantially the same as inEmbodiment 4. This light emitting device has the same effect as inEmbodiment 4.

Embodiment 6: Light Emitting Device and Method for Manufacturing thereof

In the method for manufacturing a light emitting device in thisembodiment, the side surfaces of the light emitting elements are coveredby a light reflective member, after which the light emitting element iscut into light emitting devices, and then the above-mentionedlight-transmissive members are fixed on the light emitting elements sothat the color conversion material layers will be disposed on the lightemitting elements.

The covering or the side surfaces of the light emitting elements withthe light reflective member and the cutting into individual lightemitting devices may be performed, for example, so as to obtain any ofthe configurations shown in FIGS. 13A to 13D. That is, as shown in FIG.13A, a light emitting element 14A may be configured such that asemiconductor stack 31 is stacked over a sapphire substrate (serving asa semiconductor growth substrate), electrodes 32 are disposed on thesame surface side of the semiconductor stack 31, and the side surfacesof the semiconductor stack of the light emitting element 14A and thesemiconductor stacking surface between the electrodes is covered by alight reflective member 33.

As shown in FIG. 13B, the light emitting element 14B may be configuredsuch that a semiconductor laminate 34 is obtained by removing thesapphire substrate after the semiconductor stack has been formed on thesapphire substrate (semiconductor growth substrate), the electrodes 32are disposed on the same surface side, and the light emitting element14B are reinforced by a reinforcing material 36 a. The reinforcingmaterial 36 a is preferably light reflective. As shown in FIG. 13C,regardless of whether or not the light emitting element includes asapphire substrate (a semiconductor growth substrate), the configurationmay be such that with the light emitting element 14C constituted by asemiconductor stack, the electrodes 32 are disposed on the same surfaceside, the element is mounted face-up on the substrate 36 havingterminals, the electrodes 32 of the light emitting element 14C areconnected by wires 35 to the terminals of the substrate 36, and the sidesurfaces of the semiconductor laminate of the light emitting element 14Care covered by the light reflective member 33. As shown in FIG. 13D,regardless of whether or not the light emitting element includes asapphire substrate (a semiconductor growth substrate), the configurationmay be such that in the light emitting element 14B including asemiconductor stack, the element has a vertical structure, in which theelectrodes 32 are not disposed on the same surface side and are insteaddisposed on different surface sides and mounted on the substrate 36having terminals, one of the electrodes 32 of the light emitting element14D is connected to the terminal of the substrate 36 by a wire 35, theother electrode is connected to the terminal of the substrate 36 bysolder, and the side surfaces of the semiconductor laminate of the lightemitting element 14D are covered by the light reflective member 33.

For example, as shown in FIG. 14A, a plurality of the light emittingelements 14A with the light reflective members 33 are joined to amounting substrate 50 of a light source device to which the lightemitting device will be applied, such as a linear light source. In thiscase, for example, the light emitting elements 14A are joined in topview type so that light is emitted in the direction of the arrow.

After this, the light-transmissive member 100 having a plurality ofcolor conversion material layers 12 as shown in FIG. 14B is fixed by anadhesive member or by fitting so that the color conversion materiallayers 12 are disposed on the respective light emitting elements 14A asshown in FIG. 14C. This allows light emitting devices to be obtained inwhich a plurality of the light emitting elements 14A are arranged.

Then, the light reflective sheet 11 of the light-transmissive member 10and the mounting substrate 50 may be divided by cutting with a dicer orthe like between the light emitting elements 14A to obtain lightemitting devices including a single light emitting element.

Accordingly, fixing the light-transmissive member after secondarymounting of the light emitting elements can avoid hysteresis of theresin curing and element mounting in the assembly step. The hysteresisof solder reflow or the like during secondary mounting can also beavoided.

Modification Example 8: Method for Manufacturing Light Emitting Device

In this modification example, as shown in FIG. 15A, for example, thelight emitting elements 14A are joined to the mounting substrate 50 toobtain a side-view type light emitting device so that light is emittedin the direction of the arrow. After this, the light-transmissive member100 including a plurality of color conversion material layers 12 isfixed by an adhesive member to the mounting substrate 50 so as to besubstantially perpendicular to the mounting substrate 50 and so that thecolor conversion material layers 12 are disposed on the respective lightemission surfaces of the light emitting elements 14A. This allows lightemitting devices to be obtained in which a plurality of the lightemitting elements 14A are arranged.

The light emitting device of the present invention can be used forbacklight light sources of liquid crystal displays, various kinds oflighting fixtures, and various kinds of display devices such as largedisplays, advertisements and destination guides, and image readingdevices in digital video cameras, facsimiles, copiers, scanners and thelike, and projector devices. It is to be understood that although thepresent invention has been described with regard to preferredembodiments thereof, various other embodiments and variants may occur tothose skilled in the art, which are within the scope and spirit of theinvention, and such other embodiments and variants are intended to becovered by the following claims.

What is claimed is:
 1. A light emitting device comprising: a first light emitting element having a first electrode formation surface on which a pair of electrodes are arranged, a first light extraction surface opposite from the first electrode formation surface, and a first side surface extending between the first electrode formation surface and the first light extraction surface; a second light emitting element having a second electrode formation surface on which a pair of electrodes are arranged, a second light extraction surface opposite from the second electrode formation surface, and a second side surface extending between the second electrode formation surface and the second light extraction surface; a first color conversion material layer having a first color conversion surface facing the first light extraction surface of the first light emitting element; a second color conversion material layer having a second color conversion surface facing the second light extraction surface of the second light emitting element; a support member supporting the first color conversion material layer and the second color conversion material layer; and a light reflective member covering the first side surface of the first light emitting element and the second side surface of the second light emitting element, at least a part of an upper surface of the light reflective member being positioned closer to the support member than the first color conversion material layer and the second color conversion material layer, a thickness of the light reflective member as measured in a direction orthogonal to a surface of the support member is larger at a center position between the first light emitting element and the second light emitting element than at a position adjacent to the first light emitting element or at a position adjacent to the second light emitting element.
 2. The light emitting device according to claim 1, further comprising a third light emitting element having a third electrode formation surface on which a pair of electrodes are arranged, a third light extraction surface opposite from the third electrode formation surface, and a third side surface extending between the third electrode formation surface and the third light extraction surface; a third color conversion material layer having a third color conversion surface facing the third light extraction surface of the third light emitting element, wherein the light reflective member covers the third side surface of the third light emitting element, and the at least the part of the upper surface of the light reflective member is positioned closer to the support member than the third color conversion material layer.
 3. The light emitting device according to claim 1, wherein an outer edge of the first light emitting element is disposed inside of an outer edge of the first color conversion material layer in a plan view.
 4. The light emitting device according to claim 1, wherein the light reflective member is in contact with the support member.
 5. The light emitting device according to claim 1, wherein the first color conversion material layer is in contact with the support member.
 6. The light emitting device according to claim 1, wherein the first light extraction surface of the first light emitting element and the second light extraction surface of the second light emitting element are arranged on the same plane.
 7. The light emitting device according to claim 1, further comprising a substrate on which the first light emitting element and the second light emitting element are arranged.
 8. The light emitting device according to claim 2, wherein an outer edge of the first light emitting element is disposed inside of an outer edge of the first color conversion material layer in a plan view.
 9. The light emitting device according to claim 2, wherein the light reflective member is in contact with the support member.
 10. The light emitting device according to claim 2, wherein the first color conversion material layer is in contact with the support member.
 11. The light emitting device according to claim 2, wherein the first light extraction surface of the first light emitting element, the second light extraction surface of the second light emitting element, and the third light extraction surface of the third light emitting element are arranged on the same plane.
 12. The light emitting device according to claim 2, further comprising a substrate on which the first light emitting element, the second light emitting element, and the third light emitting element are arranged.
 13. The light emitting device according to claim 3, wherein the light reflective member is in contact with the support member.
 14. The light emitting device according to claim 3, wherein the first color conversion material layer is in contact with the support member.
 15. The light emitting device according to claim 3, wherein the first light extraction surface of the first light emitting element and the second light extraction surface of the second light emitting element are arranged on the same plane.
 16. The light emitting device according to claim 3, further comprising a substrate on which the first light emitting element and the second light emitting element are arranged.
 17. The light emitting device according to claim 4, wherein the first color conversion material layer is in contact with the support member.
 18. The light emitting device according to claim 4, wherein the first light extraction surface of the first light emitting element and the second light extraction surface of the second light emitting element are arranged on the same plane.
 19. The light emitting device according to claim 4, further comprising a substrate on which the first light emitting element and the second light emitting element are arranged.
 20. The light emitting device according to claim 5, wherein the first light extraction surface of the first light emitting element and the second light extraction surface of the second light emitting element are arranged on the same plane. 